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Technical Guide

Hastelloy G-3 (UNS N06985 / W.Nr 2.4619): Ni-Cr-Mo-Cu Alloy for Chemical Processing

UNS N06985 / W.Nr 2.4619 (EN NiCr22Mo7Cu) — Nickel-chromium-molybdenum-copper corrosion-resistant alloy for wet phosphoric acid, sulfuric & nitric acid, and flue-gas-desulfurization (FGD) service. Manufacturer & global supplier.

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Hastelloy G-3 nickel-chromium-molybdenum-copper corrosion-resistant alloy plate and welded chemical processing equipment
Hastelloy G-3 corrosion-resistant alloy for phosphoric/sulfuric acid and FGD process equipment.

⚡ Hastelloy G-3 Quick Specs

N06985
2.4619
NiCr22Mo7Cu
Ni-Cr-Fe-Mo-Cu
8.14 g/cm³
1260–1343°C
≥621 MPa
≥241 MPa
≥45%
≤400°C
≤0.015%
Wet H₃PO₄ / H₂SO₄

1. Introduction: Why Hastelloy G-3?

Hastelloy G-3 (UNS N06985, W.Nr 2.4619, EN NiCr22Mo7Cu) is a nickel-chromium-iron alloy with deliberate additions of molybdenum and copper. It is the improved, lower-carbon successor to Hastelloy G-2, engineered to deliver a broad, well-balanced resistance to both oxidizing and reducing chemical environments while being exceptionally easy to weld.

The key design change versus G-2 is the ultra-low carbon (≤0.015%) together with tighter control of silicon and other minor elements. This dramatically reduces the risk of intergranular and knife-line attack in the weld heat-affected zone (HAZ) and improves overall fabricability. Chromium provides resistance to oxidizing acids such as nitric acid and wet chlorine, while nickel, molybdenum, and copper provide resistance to reducing acids — most notably wet phosphoric acid and sulfuric acid. These attributes make Hastelloy G-3 a standard material for phosphoric-acid production, acid recovery, and flue-gas-desulfurization (FGD) systems.

Hangbo Alloy Group supplies Hastelloy G-3 as plate, sheet, strip, bar, seamless and welded pipe/tube, fittings, and matching welding consumables, all solution-annealed and certified — a dependable Hastelloy G-3 supplier for global chemical and environmental projects.

Need Hastelloy G-3 Plate, Pipe or Welding Wire?

Hangbo Alloy Group manufactures and supplies Hastelloy G-3 (UNS N06985 / W.Nr 2.4619) plate, sheet, bar, seamless & welded pipe/tube, fittings, and ERNiCrMo-12 welding consumables — all solution-annealed with full material certification.

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2. Chemical Composition

Hastelloy G-3 achieves its balanced corrosion resistance through a synergistic mix of chromium (oxidizing resistance), molybdenum (reducing acid, pitting and crevice resistance), and copper (sulfuric and phosphoric acid resistance). The high iron content reduces cost and improves formability, while the ultra-low carbon prevents sensitization and intergranular corrosion after welding.

ElementStandard Range (wt%)Typical ValueRole in the Alloy
Nickel (Ni)Balance~46Austenitic matrix; SCC resistance in chlorides
Chromium (Cr)21.0 – 23.522.2Oxidizing-acid & wet-chloride resistance
Iron (Fe)18.0 – 21.019.5Cost control; formability
Molybdenum (Mo)6.0 – 8.07.0Reducing-acid; pitting & crevice resistance
Copper (Cu)1.5 – 2.51.9Sulfuric & phosphoric acid resistance
Cobalt (Co)≤ 5.02.0Solid-solution; minor
Tungsten (W)≤ 1.51.0Strength; pitting resistance
Niobium + Tantalum (Nb+Ta)≤ 0.500.3Stabilization
Carbon (C)≤ 0.0150.010Prevents sensitization / IG corrosion
Manganese (Mn)≤ 1.00.8Deoxidation; sulfur control
Silicon (Si)≤ 1.00.4Deoxidation; controlled for HAZ stability
Phosphorus (P)≤ 0.040.020Impurity control
Sulfur (S)≤ 0.030.010Impurity control for hot ductility

3. Physical Properties

The physical properties of Hastelloy G-3 are typical of nickel-base corrosion-resistant alloys: moderate density, low thermal conductivity, and a thermal-expansion coefficient close to that of austenitic stainless steels.

PropertyValueNotes
Density8.14 g/cm³ (0.294 lb/in³)Typical
Melting Range1260 – 1343 °C (2300 – 2450 °F)Solidus – liquidus
Thermal Expansion (20–100°C)~14.6 × 10−6 /°CMean coefficient
Thermal Expansion (20–600°C)~15.1 × 10−6 /°CMean coefficient
Thermal Conductivity~10.0 W/(m·K) at 25°CLow
Specific Heat~453 J/(kg·K)At room temperature
Modulus of Elasticity~199 GPa (28.9 × 10³ ksi)Tension, RT
Magnetic PropertiesNon-magnetic (austenitic)

4. Mechanical Properties

4.1 Room-Temperature Properties (Solution-Annealed)

The following are typical minimum and typical values for solution-annealed product forms (sheet, plate, bar, pipe):

PropertyTypical / Minimum ValueCondition
Tensile Strength (Rm)≥ 621 MPa (90 ksi); typ. ~690 MPaSolution-annealed
Yield Strength (Rp0.2)≥ 241 MPa (35 ksi); typ. ~320 MPaSolution-annealed
Elongation (A)≥ 45%; typ. ~50%Solution-annealed
Hardness≤ 100 HRBSolution-annealed

4.2 Service-Temperature Considerations

Hastelloy G-3 is a corrosion-resistant alloy, not a high-temperature creep alloy. It is suitable for long-term pressure service up to about 400°C (with short excursions to ~550°C). Above roughly 420°C under sustained load, sigma-phase embrittlement can occur, so it is not used for high-temperature creep components.

5. Welding Characteristics & Fabrication

5.1 Weldability

Hastelloy G-3 has excellent weldability and very low sensitivity to weld cracking. Its ultra-low carbon prevents sensitization and intergranular corrosion in the heat-affected zone, so fabricated equipment can often be placed in service without post-weld heat treatment. It is joined by GTAW (TIG), GMAW (MIG), and SMAW using matching or over-alloyed fillers (ASME welding group F-No. 44).

5.2 Recommended Filler Metals & Parameters

ItemRecommendation
Bare wire / rodERNiCrMo-12 (AWS A5.14)
Covered electrodeENiCrMo-12 (AWS A5.11)
Over-alloyed optionERNiCrMo-10 / ENiCrMo-10
Shielding gas (GTAW/GMAW)High-purity argon; argon-helium mixes
Post-weld heat treatmentNormally not required
Surface preparationClean, degreased; avoid contamination, use dedicated tools

5.3 Forming & Machining

  • Hot working: Perform in the 900–1150°C range; solution anneal after hot forming to restore corrosion resistance.
  • Cold working: Good formability; work in the solution-annealed condition, with intermediate annealing for heavy reductions.
  • Machining: Work-hardens; use rigid setups, positive rake angles, and moderate cutting speeds with coolant.

Buy Hastelloy G-3 — Trusted Manufacturer & Supplier

Contact Hangbo Alloy Group for certified Hastelloy G-3 (UNS N06985) plate, pipe, bar, fittings, and ERNiCrMo-12 welding consumables. Competitive Hastelloy G-3 price, fast delivery, full EN 10204 3.1 MTR and third-party inspection.

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6. Corrosion Resistance

The balanced chemistry of Hastelloy G-3 gives it unusually broad resistance to general and localized corrosion as well as to stress-corrosion cracking:

  • Wet phosphoric acid: Excellent resistance to dihydrate-process phosphoric acid containing fluorides, chlorides, and sulfates; a standard material for phosphoric-acid evaporators and reactors.
  • Sulfuric acid: Good resistance to hot,medium-concentration sulfuric acid and to contaminated/reducing sulfuric streams (acid recovery, pickling).
  • Nitric acid: Good resistance to contaminated and reducing nitric acid (pure concentrated nitric favors higher-chromium alloys).
  • Mixed acids: Resists nitric-phosphoric-sulfuric blends, fluosilicic and sulfate solutions, and hydrofluoric-acid environments.
  • Pitting & crevice corrosion: High molybdenum gives strong resistance in chloride-bearing media.
  • Stress-corrosion cracking: Nickel matrix provides exceptional resistance to chloride SCC.
  • Weld HAZ immunity: Ultra-low carbon prevents sensitization and intergranular corrosion in the as-welded condition.

7. Applications by Industry

7.1 Chemical Processing & Fertilizers

  • Wet phosphoric acid evaporators, reactors, filters, and heat exchangers
  • Sulfuric acid recovery, regeneration, and pickling systems
  • Mixed-acid and fertilizer (nitric-phosphoric-sulfuric) equipment, valves, pumps
  • Organic-acid (acetic, formic) reactors and exchangers

7.2 Flue-Gas Desulfurization (FGD) & Pollution Control

  • FGD scrubbers, absorber towers, and quenchers
  • Dampers, outlet ducts, stack liners, and demister supports
  • Equipment exposed to acid condensate and wet, chlorinated flue gas

7.3 Oil & Gas and Other Process Industries

  • Sour (H₂S / CO₂ / Cl⁻) service tubulars and components meeting NACE MR0175 / ISO 15156
  • Pulp & paper bleach washers and wet-process metallurgy equipment
  • Tank liners, heat exchangers, and piping handling aggressive mixed acids

8. Product Forms & Availability

Hangbo Alloy Group supplies Hastelloy G-3 (UNS N06985 / W.Nr 2.4619) in all standard product forms, solution-annealed and certified to ASTM/ASME specifications:

Product FormApplicable StandardTypical Size Range
Plate, Sheet, StripASTM B582 / ASME SB5820.5 – 100 mm plate; coils/strip 0.1 – 12 mm
Bar, Rod, ForgingsASTM B581 / ASME SB581Diameter 5 – 300 mm
Seamless Pipe & TubeASTM B622 / ASME SB622OD 6 – 219 mm
Welded Pipe & TubeASTM B619 / B626Custom (ERW/EFW)
Fittings & FlangesASTM B366 / ASME SB366Elbows, tees, reducers, WNRF/SO/blind
Welding ConsumablesAWS A5.14 ERNiCrMo-12Wire 0.8 – 2.4 mm; electrodes

All products are supplied with EN 10204 Type 3.1 material certificates (chemical analysis, mechanical test results, and conformance to the ordered ASTM/ASME specification).

9. Applicable Standards & Specifications

StandardDescription
UNS N06985Unified Numbering System designation
W.Nr 2.4619 / EN NiCr22Mo7CuGerman / European designation
ASTM B581Bar, rod, and forgings
ASTM B582Plate, sheet, and strip
ASTM B619 / B622 / B626Welded pipe / seamless pipe & tube / welded tube
ASTM B366Factory-made wrought fittings
ASME SB equivalentsBPVC material specifications (SB581, SB582, SB619, SB622, SB626, SB366)
NACE MR0175 / ISO 15156Sour (H₂S) oil & gas service
GB NS3403Chinese equivalent grade
AWS A5.14 / A5.11ERNiCrMo-12 / ENiCrMo-12 welding consumables

10. Comparison: Hastelloy G-3 vs G-2 vs C-276 vs C-22

PropertyHastelloy G-3Hastelloy G-2Hastelloy C-276Hastelloy C-22
UNSN06985N06975N10276N06022
Nominal Cr %22~221521
Nominal Mo %7~181613
Cu %1.5 – 2.5≤ 0.5——
W %≤ 1.5≤ 1.03 – 4.52.5 – 3.5
Carbon≤ 0.015%≤ 0.02%≤ 0.010%≤ 0.015%
Best atPhosphoric/sulfuric + weldabilityOlder G successorStrong reducing acidsBroad oxidizing+reducing
Relative costModerateObsoleteHigherHighest

Selection guide: Choose Hastelloy G-3 for phosphoric/sulfuric acid, mixed-acid, and FGD service where excellent weldability and a favorable cost balance matter. Choose C-276 or C-22 when service involves strong reducing acids (e.g., hydrochloric) or severe pitting/crevice attack that demands higher molybdenum/tungsten. G-2 is essentially superseded by G-3 for new designs.

11. Frequently Asked Questions (FAQ)

Q1: What is Hastelloy G-3?

Hastelloy G-3 (UNS N06985 / W.Nr 2.4619, EN NiCr22Mo7Cu) is a nickel-chromium-iron alloy with additions of molybdenum and copper. It is the upgraded successor to Hastelloy G-2, with ultra-low carbon and tighter control of silicon and other minor elements to improve weldability and resistance to heat-affected-zone (HAZ) corrosion. It resists both oxidizing and reducing chemicals and is especially suited to wet phosphoric acid, sulfuric acid, nitric acid, and flue-gas-desulfurization (FGD) service.

Q2: What is the chemical composition of Hastelloy G-3?

Limiting composition of Hastelloy G-3 (UNS N06985): Nickel balance; Chromium 21.0-23.5%; Iron 18.0-21.0%; Molybdenum 6.0-8.0%; Copper 1.5-2.5%; Cobalt ≤5.0%; Tungsten ≤1.5%; Niobium+Tantalum ≤0.50%; Manganese ≤1.0%; Silicon ≤1.0%; Carbon ≤0.015%; Phosphorus ≤0.04%; Sulfur ≤0.03%. The ultra-low carbon prevents sensitization and intergranular corrosion in the weld HAZ.

Q3: What are the mechanical properties of Hastelloy G-3?

In the solution-annealed condition, Hastelloy G-3 typically meets a minimum tensile strength of 621 MPa (90 ksi) with typical values around 690 MPa, a minimum yield strength of 241 MPa (35 ksi) with typical values near 320 MPa, elongation of at least 45% (typically ~50%), and hardness not exceeding about 100 HRB. It is ductile, formable, and non-magnetic.

Q4: What is the density and melting range of Hastelloy G-3?

Hastelloy G-3 has a density of about 8.14 g/cm³ (0.294 lb/in³). Its melting range is approximately 1260-1343°C (2300-2450°F). The mean coefficient of thermal expansion is about 14.6 ×10⁻⁶/°C over 20-100°C (rising to ~15.1 ×10⁻⁶/°C at 600°C), thermal conductivity about 10.0 W/(m·K) at 25°C, and modulus of elasticity about 199 GPa. It is non-magnetic.

Q5: What acids and environments is Hastelloy G-3 resistant to?

Hastelloy G-3 resists hot sulfuric acid, wet (dihydrate) phosphoric acid, contaminated/reducing nitric acid, mixed acid streams, fluosilicic and sulfate solutions, and hydrofluoric acid environments. Its chromium gives oxidizing-acid resistance while nickel, molybdenum, and copper provide reducing-acid resistance. It is widely used in flue-gas-desulfurization (FGD) scrubbers and in oxidizing-chloride and sour (H2S/CO2/Cl⁻) oil-and-gas service meeting NACE MR0175/ISO 15156.

Q6: How does Hastelloy G-3 compare to Hastelloy G-2?

G-3 is the improved, lower-carbon successor to G-2. By dropping carbon from ~0.05% to ≤0.015% and tightening silicon and other minor elements, G-3 greatly reduces intergranular and knife-line attack in the weld heat-affected zone and improves fabricability, while retaining (and in many acids exceeding) G-2's corrosion resistance. G-3 is generally the preferred choice for new equipment; G-2 is now largely obsolete.

Q7: How does Hastelloy G-3 compare to Hastelloy C-276 and C-22?

C-276 and C-22 are higher-molybdenum, tungsten-containing Ni-Cr-Mo alloys with superior resistance to strong reducing acids (e.g., hydrochloric) and to localized pitting/crevice corrosion, but they lack G-3's copper and cost more. G-3 offers an excellent, lower-cost balance of oxidizing- and reducing-acid resistance plus outstanding weldability, making it ideal for phosphoric/sulfuric acid and FGD service where C-276/C-22 would be over-specified.

Q8: Is Hastelloy G-3 weldable, and what filler metal is used?

Yes. Hastelloy G-3 has excellent weldability by GTAW (TIG), GMAW (MIG), and SMAW using matching filler metals ERNiCrMo-12 (AWS A5.14) / ENiCrMo-12 (AWS A5.11), or over-alloyed fillers such as ERNiCrMo-10/ENiCrMo-10. The ultra-low carbon gives very low sensitivity to weld cracking and prevents HAZ sensitization, so post-weld heat treatment is normally not required. ASME welding group F-No. 44. Clean joints and inert shielding are essential.

Q9: What heat treatment does Hastelloy G-3 require?

Hastelloy G-3 is supplied in the solution-annealed condition (typically 1040-1090°C, rapid water quench or fast cool) and is not age-hardenable. Post-weld heat treatment is normally unnecessary because the alloy does not sensitize. For stress relief of cold-worked or thick welded fabrications, a low-temperature treatment around 430-480°C for 1-2 hours (air cool) may be used.

Q10: What is Hastelloy G-3 used for?

Primary applications are in chemical processing and pollution control: wet-process phosphoric acid evaporators, reactors, filters and heat exchangers; sulfuric acid recovery and pickling systems; mixed-acid and fertilizer (nitric-phosphoric-sulfuric) equipment; flue-gas-desulfurization (FGD) scrubbers, dampers, ducts and stack liners; and sour oil-and-gas tubulars and components meeting NACE MR0175. It is also used in pulp & paper and wet-process metallurgy.

Q11: What standards and specifications apply to Hastelloy G-3?

Key standards: UNS N06985; W.Nr 2.4619 (EN NiCr22Mo7Cu); ASTM B581 (bar), B582 (plate/sheet/strip), B619 (welded pipe), B622 (seamless pipe & tube), B626 (welded tube), B366 (fittings) and the ASME SB equivalents; NACE MR0175 / ISO 15156 for sour service; GB NS3403; and welding consumables AWS A5.14 ERNiCrMo-12 / A5.11 ENiCrMo-12.

Q12: What product forms does Hastelloy G-3 come in?

Hangbo Alloy Group supplies Hastelloy G-3 as plate, sheet and strip (ASTM B582), bar, rod and forgings (B581), seamless pipe and tube (B622), welded pipe and tube (B619/B626), butt-weld fittings and flanges (B366), and matching welding consumables (ERNiCrMo-12). All product forms are supplied solution-annealed with full EN 10204 3.1 material certification.

Q13: What is the price and lead time for Hastelloy G-3, and where can I buy it?

Hastelloy G-3 is a premium corrosion-resistant nickel alloy. Typical market pricing ranges from roughly $40-70/kg for plate, sheet, bar and pipe, depending on product form, thickness, certification, and current nickel/molybdenum market conditions. Lead times are typically 3-6 weeks for stock sizes and 8-14 weeks for custom-forged or certified lots. Hangbo Alloy Group is a global Hastelloy G-3 manufacturer and supplier — contact serena@hangboalloy.com for a competitive quote.